Rolla, Mo., Sept. 18, 2017 (GLOBE NEWSWIRE) — A physics professor at Missouri University of Science and Technology will lead a four-year effort to spur research, development and commercial adoption of a new class of oxide semiconductors that outperform silicon-based transistors and could lead to new uses for flexible displays.
A team led by Dr. Julia E. Medvedeva, a professor of physics at Missouri S&T, was recently awarded a $1.6 million grant from the U.S. National Science Foundation to study the properties of amorphous oxide materials and to develop an open-access database for other researchers to use. The four-year grant is part of an NSF program called Designing Materials to Revolutionize and Engineer our Future (DMREF) and also involves researchers from Northwestern University. It takes effect Oct. 1.
The oxide semiconductors Medvedeva will study demonstrate seemingly contradictory properties, such as optical transparency and electrical conductivity. These properties make the semiconductors ideal for use in flat-panel displays that consume less power while creating brighter images. Already in use in display panels made by Apple, Sharp, Dell, LG and Razer Inc., these oxide semiconductors also allow electrons to transmit much more rapidly than through silicon – as high as 50 times the electron mobility of “amorphous” silicon, Medvedeva says. That allows for higher pixel density, which in turn leads to better screen resolution.
And because the amorphous form of these oxides can be grown at room temperature and on a variety of substrate materials, they can be produced at larger scales and at lower costs than silicon or other crystalline materials, Medvedeva says.
“This is very fundamental research,” she adds, but notes that the results could enable advances in flexible-panel displays and wearable electronics, smart windows for homes and cars, and solar panels that could wrap around a surface to capture as much sunlight as possible.
“The advantages of the amorphous oxide materials are numerous,” Medvedeva says, “but our fundamental understanding of their intriguing combination of properties is very limited.”
Crystalline structures such as silicon behave in predictable ways, she says.
“Take a diamond, for instance, the hardest material on earth,” says Medvedeva. “The very reasons for the exceptional hardness of diamond – the high symmetry of the atomic arrangement and the strong interatomic bonds – are responsible for the gem’s major flaw.
“A diamond is brittle,” she adds. “A sharp blow, cleaving perfectly along specific planes of atoms, can shatter it. Because of the predictable directions of the structure, we will always achieve the same, predictable results. Giving up the perfection of the ordered arrangement of atoms altogether may lead to a superior material without trade-offs.”
Amorphous materials possess a “disorganized structure,” Medvedeva says. “Their lack of periodicity (or recurrent characteristics), unlike a crystalline structure, makes our studies of such materials extremely challenging. We cannot apply what we know about crystalline structures to amorphous structures because they cannot be reduced to an ordered set of building blocks.”
What physicists and materials scientists do know about amorphous materials is that “they have a smooth surface, with no grain,” Medvedeva says. “They’re also mechanically flexible,” which means they can be bent or twisted – imagine flexible solar cells that can wrap around a rooftop or even an entire building. They also can be “tuned” to either reflect, transmit or absorb light, properties that could lead to advances in smart windows, among other applications.
Through the NSF grant, Medvedeva will develop computer models to show how amorphous oxides act under certain conditions at the atomic level. “We want to start by looking at the way atoms are put together,” she says, “because structure determines everything.”
Medvedeva will develop simulations of structures under various conditions – such as melting, then rapidly cooling a structure, adjusting its composition or growth conditions – and record how these conditions affect the material’s mechanical, electrical, optical and thermal properties. She will simulate both large experiments – “thousands of atoms” at a time – and small ones that involve fewer atoms but “a lot of unique configurations.”
From these simulations, she will develop a database that will eventually be accessible to researchers worldwide. Medvedeva envisions creating an open-source software she calls the Amorphous Materials Analysis Database that other scientists could use and contribute to. Her hope is that this approach will “bring computer-aided design of amorphous materials to a new level.”
In August, Medvedeva and Northwestern University researchers Dr. Bruce Buchholz and Dr. Robert P.H. Chang published a paper on the topic in the journal Advanced Electronic Materials. The paper, titled “Recent Advances in Understanding the Structure and Properties of Amorphous Oxide Semiconductors,” is available online at http://onlinelibrary.wiley.com/doi/10.1002/aelm.201700082/full.
The DMREF award to Missouri S&T is one of 23 in the nation in 2017. DMREF’s goal is to “deploy advanced materials at least twice as fast as possible today, at a fraction of the cost.”
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